Stability and infrared spectra of mono-, di-, and trichloromethanol
TJ Wallington, WF Schneider, I Barnes, KH Becker…
Index: Wallington; Schneider; Barnes; Becker; Sehested; Nielsen Chemical Physics Letters, 2000 , vol. 322, # 1-2 p. 97 - 102
Full Text: HTML
Citation Number: 41
Abstract
CH2ClOH, CHCl2OH, and CCl3OH were prepared by UV irradiation of CH3OH/Cl2/N2 gas mixtures. Absorption cross-sections (base e) of σ (CH2ClOH) at 1093 cm− 1= 6.16× 10− 19, σ (CHCl2OH) at 1109 cm− 1= 1.22× 10− 18, and σ (CCl3OH) at 1119 cm− 1= 8.96× 10− 19 cm2 molecule− 1 were determined. The chlorinated methanols decayed with first-order kinetics to HCl and the corresponding carbonyl compound. The decay rates increased ...
Related Articles:
Rate coefficients for the reactions of chlorine atoms with methanol and acetaldehyde
[Tyndall; Orlando; Kegley-Owen; Wallington; Hurley International Journal of Chemical Kinetics, 1999 , vol. 31, # 11 p. 776 - 784]
[Kunttu, Henrik; Dahlqvist, Martti; Murto, Juhani; Raesaenen, Markku Journal of Physical Chemistry, 1988 , vol. 92, # 6 p. 1495 - 1502]
[Tyndall, Geoffrey S.; Wallington, Timothy J.; Hurley, Michael D.; Schneider, William F. Journal of Physical Chemistry, 1993 , vol. 97, # 8 p. 1576 - 1582]
[Nummert, Vilve; Piirsalu, Mare Journal of Physical Organic Chemistry, 2002 , vol. 15, # 6 p. 353 - 361]
[Merenyi, Gabor; Lind, Johan; Eberson, Lennart Acta Chemica Scandinavica, 1998 , vol. 52, # 1 p. 62 - 66]