Microbiological Transformations 60. Enantioconvergent Baeyer–Villiger Oxidation via a Combined Whole Cells and Ionic Exchange Resin??Catalysed Dynamic Kinetic …

MC Gutiérrez, R Furstoss…

Index: Gutierrez, Maria-Concepcion; Furstoss, Roland; Alphand, Veronique Advanced Synthesis and Catalysis, 2005 , vol. 347, # 7-8 p. 1051 - 1059

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Citation Number: 44

Abstract

Abstract A dynamic kinetic resolution process was applied to an enantioconvergent microbial Baeyer–Villiger oxidation of benzyloxycyclopentanone, rac-1. This was achieved by combining a whole cell-based kinetic resolution and an anion exchange resin-catalysed in situ racemisation. Several resins were screened according to their capacity to catalyse the racemisation of 1. As compared to our previous results, the presence of weakly basic ...