Synthesis and reduction of 2, 2??diaryl??1??nitroethylenes by using a chiral and a non chiral NADH model in the pyrrolopyridine series
…, G Dupas, G Quéguiner, J Bourguignon
Index: Levacher, Vincent; Valque, Claude; Coupa, Sophie; Dupas, Georges; Queguiner, Guy; Bourguignon, Jean Journal of Heterocyclic Chemistry, 1996 , vol. 33, # 4 p. 1211 - 1215
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Abstract
Abstract Reduction of 2, 2-diphenyl-1-nitroethylene (1) and 2-(2-pyridyl)-2-phenyl-1- nitroethylene (5) is achieved by using the NADH model in the pyrrolopyridine series 2a to give 2, 2-diphenyl-1-nitroethane (3) and 2-(2-pyridyl)-2-phenyl-1-nitroethane (7) respectively in 40% yield. The asymmetric reduction of 2-(2-pyridyl)-2-phenyl-1-nitroethylene by the chiral NADH model 2b is studied. Thus, 2-(2-pyridyl)-2-phenyl-1-nitroethane (7) is ...
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