Synthesis of fluorinated imines and carbodiimides from azides via aza-Wittig reaction

Y Wu, Q Sun, J Deng, W Tian

Index: Wu, Yongming; Sun, Qingrui; Deng, Juan; Tian, Weisheng Journal of Fluorine Chemistry, 2006 , vol. 127, # 9 p. 1152 - 1157

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Citation Number: 6

Abstract

The Staudinger reaction of fluoroalkylazides were studied. A series of N-fluoroalkylimines were synthesized via aza-Wittig reaction of N-fluoroalkyliminophosphoranes. The N, N′- difluoroalkylated carbodiimide was also synthesized via the reaction of N- fluoroalkyliminophosphoranes with carbon dioxide or carbon disulfide.