Tetrahedron letters

Syn-Oxidative cyclizations of trishomoallylic alcohols: Stereoselective and stereospecific synthesis of trans-tetrahydropyranyl alcohols

FE McDonald, AD Singhi

Index: McDonald, Frank E.; Singhi, Aatur D. Tetrahedron Letters, 1997 , vol. 38, # 44 p. 7683 - 7686

Full Text: HTML

Citation Number: 19

Abstract

Trifluoroacetylperrhenate promotes the hydroxyl-directed syn-oxidative cyclization of trishomoallylic alcohols. The cyclization reaction is highly stereospecific and stereoselective, providing a novel and efficient synthesis of trans-2, 6-disubstituted tetrahydropyranyl alcohols.

Related Articles:

Enantiopure 1, 5-diols from dynamic kinetic asymmetric transformation. Useful synthetic intermediates for the preparation of chiral heterocycles

[Leijondahl, Karin; Boren, Linnea; Braun, Roland; Baeckvall, Jan-E. Organic Letters, 2008 , vol. 10, # 10 p. 2027 - 2030]

A highly regio-and stereoselective synthesis of internal olefins via an elimination of trimethylstannyl group

[Murayama, Eigoro; Uematsu, Masahiro; Nishio, Hiroyuki; Sato, Tadashi Tetrahedron Letters, 1984 , vol. 25, # 3 p. 313 - 316]

Balancing hydrophobic and hydrophilic forces at the water/vapor interface: Surface structure of soluble alcohol monolayers

[Kamezawa, Makoto; Raku, Takao; Tachibana, Hojun; Ohtani, Takehiko; Naoshima, Yoshinobu Bioscience, Biotechnology, and Biochemistry, 1994 , vol. 58, # 3 p. 598 - 599]

More Articles...