Etude de la reactivite du tris (tertiobutyl) phenyldithiophosphorane
J Navech, M Revel, R Kraemer
Index: Navech, J.; Revel, M.; Kraemer, R. Tetrahedron Letters, 1985 , vol. 26, # 2 p. 207 - 210
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Citation Number: 17
Abstract
Abstract Heating of tris (tertiobutyl) phenyldithiophosphorane gives rise to an isomer with a tetracoordinated phosphorus atom. The action of triphenylphosphine loads to a tricyclophosphathiane which can be transformed in diphosphene by an excess of triphenylphosphine. Reactions with various nucleophilic derivatives (pyridine, triethylamine, diethylamine, butylamine, water, tetraphenylarsonium chloride) are described.
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