Reactions of allylic compounds such as allyl alcohols, allyl ethers, and allylamines using trans-Mo (N2) 2 (Ph2PCH2CH2PPh2) 2

T Tatsumi, K Hashimoto, H Tominaga, Y Mizuta…

Index: Tatsumi, T.; Hashimoto, K.; Tominaga, H.; Mizuta, Y.; Hata, K.; et al. Journal of Organometallic Chemistry, 1983 , vol. 252, # 1 p. 105 - 112

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Citation Number: 37

Abstract

Abstract Double-bond migration of allylic alcohols and allylic alkyl ethers was catalytically effected with trans-Mo (N 2) 2 (dpe) 2 (dpe= Ph 2 PCH 2 CH 2 PPh 2). Decarbonylation occurred simultaneously in the case of allyl alcohol. Diallyl ether and allyl phenol ether gave the fragmentation products presumably through initial oxidative addition of the allyl O bond. Allylamine was converted to N-propylideneallylamine and NH 3. N, N- ...