Isomerization and cyclization of octatrienes

EA Zuech, DL Crain…

Index: Zuech,E.A. et al. Journal of Organic Chemistry, 1968 , vol. 33, p. 771 - 775

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Citation Number: 16

Abstract

Interactions of the readily available mixture of 1, 3, 6-and 1, 3, 7-octatrienes with the alkali metal salts of alkyl amides have resulted in both a selective isomerization and a cyclization. In the first instance, potassium salts have selectively transformed the 1, 3, 6-octatrienes to 2, 4, 6-octatrienes and, in the second, the octatriene mixture has been converted into methylcycloheptadienes (IV). By a series of glpc and nmr determinations and by ...