The Journal of Organic Chemistry

General synthesis of. omega.-acetylenic vinyl esters and ethers

MC Croudace, NE Schore

Index: Croudace, Michael C.; Schore, Neil E. Journal of Organic Chemistry, 1981 , vol. 46, p. 5357 - 5363

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Citation Number: 40

Abstract

Vinyl ethers of the general structure CH2= CHO (CH2), C= CH and vinyl esters of the general structure CH+ 2 HOC (O)(CH &, MH have been prepared by mild elimination methods from the correspond& u-acetylenic alcohols and acids. A two-step procedure involving addition of alcohol to (trimethylsily1) oxirane followed by silanol elimination, and only slightly modified from the one developed by Hudrlik, provides the vinyl ethers in ...