Inorganic chemistry

Oxo Transfer from Nitrogen Dioxide to Nitrito Group in a Copper (II) Complex

K Gogoi, H Deka, V Kumar, B Mondal

Index: Kumar, Vikash; Kalita, Aswini; Mondal, Biplab Dalton Transactions, 2013 , vol. 42, # 46 p. 16264 - 16267

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Abstract

Reaction of Cu (II) complex [CuII (LH)(O2CCH3) 2][LH= 4, 6-di tert-butyl-2-((2-picolyl (isopropyl) amino) methyl) phenol] with equivalent amount of NO2 leads to the reduction of Cu (II) to Cu (I) with concomitant nitration at the phenol ring. Additional equivalent of NO2