Inorganica chimica acta

Reactions of Me3N with GeH3Br: evidence for stabilized germanium dihydride species

CA Heil, AD Norman

Index: Heil, Charles A.; Norman, Arlan D. Inorganica Chimica Acta, 1988 , vol. 154, p. 9 - 16

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Citation Number: 2

Abstract

Abstract Bromogermane (GeH 3 Br) and Me 3 N (1: 1 mole ratio) reaction at− 78 C yields Me 2 N· GeH 3 Br (1). 1 with H 2 O or MeOH yields (GeH 3) 2 O or MeOGeH 3, respectively. 1 with a one molar excess of Me 3 N forms (Me 3 N) 2 GeH 3 Br (2). Thermal decomposition of 2 produces mainly Ge 3 H 8 (25–30%) and Me 3 NHBr. GeH 3 Br with excess Me 3 N in Et 2 O at 0 C yields Me 3 NHBr and a species in solution formulated as Me 3 NGeH 2 (3). ...