The substitution of 5-halo-1, 2, 3-triazines with electrolytically generated superoxide
T Itoh, K Nagata, M Okada, H Takahashi, A Ohsawa
Index: Itoh, Takashi; Nagata, Kazuhiro; Okada, Mamiko; Takahashi, Hiroyuki; Ohsawa, Akio Tetrahedron, 1991 , vol. 47, # 25 p. 4317 - 4324
Full Text: HTML
Citation Number: 13
Abstract
Electrolytically generated superoxide reacted with 5-halo-1, 2, 3-triazines 1 to afford 5- hydroxy-1, 2, 3-triazines 2. Reaction of 1 with hydroxide anion or potassium superoxide resulted in complicated mixture of products, therefore the reaction was specific for electrogenerated superoxide. The reaction mechanism was investigated with electrochemical methods, and it was revealed that one electron transfer from superoxide ...
Related Articles:
Reactions of N-aminopyrazoles with halogenating reagents and synthesis of 1, 2, 3-triazines.
[Ohsawa, Akio; Kaihoh, Terumitsu; Itoh, Takashi; Okada, Mamiko; Kawabata, Chikako; et al. Chemical & Pharmaceutical Bulletin, 1988 , vol. 36, # 10 p. 3838 - 3848]
Reactions of N-aminopyrazoles with halogenating reagents and synthesis of 1, 2, 3-triazines.
[Ohsawa, Akio; Kaihoh, Terumitsu; Itoh, Takashi; Okada, Mamiko; Kawabata, Chikako; et al. Chemical & Pharmaceutical Bulletin, 1988 , vol. 36, # 10 p. 3838 - 3848]
Reactions of N-aminopyrazoles with halogenating reagents and synthesis of 1, 2, 3-triazines.
[Ohsawa, Akio; Kaihoh, Terumitsu; Itoh, Takashi; Okada, Mamiko; Kawabata, Chikako; et al. Chemical & Pharmaceutical Bulletin, 1988 , vol. 36, # 10 p. 3838 - 3848]
Reactions of N-aminopyrazoles with halogenating reagents and synthesis of 1, 2, 3-triazines.
[Ohsawa, Akio; Kaihoh, Terumitsu; Itoh, Takashi; Okada, Mamiko; Kawabata, Chikako; et al. Chemical & Pharmaceutical Bulletin, 1988 , vol. 36, # 10 p. 3838 - 3848]
Oxidation of 1-aminopyrazoles and synthesis of 1, 2, 3-triazines
[Ohsawa, Akio; Arai, Heihachiro; Ohnishi, Hidefumi; Itoh, Takashi; Kaihoh, Terumitsu; et al. Journal of Organic Chemistry, 1985 , vol. 50, # 26 p. 5520 - 5523]