Novel [2, 3]-sigmatropic rearrangement for carbon-nitrogen bond formation

…, M Fukui, A Yamashita, J Urano, S Saito

Index: Ishikawa; Kawakami; Fukui; Yamashita; Urano; Saito Journal of the American Chemical Society, 2001 , vol. 123, # 31 p. 7734 - 7735

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Citation Number: 23

Abstract

[2, 3]-Sigmatropic rearrangement is a widespread method for regiospecific carbon-carbon or carbon-heteroatom bond formation in organic synthesis, 1 and enormous examples have been reported including their applications to asymmetric synthesis and natural product synthesis. For aza-versions, 2 a number of allylchalcogenide and allylamineimide derivatives have been demonstrated to be usable for transferring amino groups to allylic ...