Oxidatively assisted nucleophilic substitution of organosilicon iodides

AI Al-Wassil, C Eaborn, AK Saxena

Index: Al-Wassil, Abdulaziz I.; Eaborn, Colin; Saxena, Anil K. Journal of the Chemical Society, Chemical Communications, 1983 , # 17 p. 974 - 975

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Abstract

The iodides (Me3Si) 3CSiMe2I,(Me3Si) 3CSiPh2I, and But3SiL react with m- chloroperoxybenzoic acid to give the hydroxides (Me3Si) 3CSiMe2OH,(Me3Si) 2C (SiPh2Me)(SiMe2OH), and But3SiOH, respectively in MeOH (Me3Si) 3CSiPh2I suggests the participation of silico-cationic intermediates.

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