The chemiluminescent Cycloreversion of an Anthracene-Benzene Biplanemer System both in the Solid State and in the Liquid State.

M Kimura, H Okamoto, S Kashino

Index: Kimura, Masaru; Okamoto, Hideki; Kashino, Setsuo Bulletin of the Chemical Society of Japan, 1994 , vol. 67, # 8 p. 2203 - 2212

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Citation Number: 17

Abstract

In the thermal [4+ 4] cycloreversions of 9-anthracenecarboxylic acid-benzene 3a, methyl 9- anthracenecarboxylate-benzene 3b, dimethyl (or diethyl) 9, 10-anthracenedicarboxylate- benzene 3c (or 3d) and anthracene-1, 4-difluoro (or dichloro) benzene 3f (or 3g) biplanemers, chemiluminescene was observed for 3a—d only in the solid state at> 120° C but not in a liquid phase, while 3f and 3g were not chemiluminescent. Efficient ...

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