Effective cleavage of ditertiary glycols via vanadium (V)-catalyzed aerobic oxidation
…, K Yoshida, T Noguchi, S Naito, N Matsumoto, Y Ema…
Index: Kirihara, Masayuki; Yoshida, Katsumi; Noguchi, Takuya; Naito, Sayuri; Matsumoto, Nobuchika; Ema, Yukinori; Torii, Motoya; Ishizuka, Yuki; Souta, Ikuo Tetrahedron Letters, 2010 , vol. 51, # 28 p. 3619 - 3622
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Citation Number: 11
Abstract
The oxidative cleavage of carbon–carbon bonds in 1,2-diols (glycols) is a very important reaction which has frequently been utilized in organic syntheses. 1 Despite the importance of the oxidative cleavage of glycols, there are not very many reagents that can be used for these reactions. 2 Representative oxidants include periodates 3 and lead tetraacetate. 4 They are classical oxidants, however, they are still the reagents of choice. Although periodates effectively ...
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