Tetrahedron letters

Silicon-phosphorus analogies rate controlling factors in SN2 (P) reactions influence of the nucleophile for a given stereochemistry

RJP Corriu, GF Lanneau, D Leclercq

Index: Corriu, Robert J.P.; Lanneau, Gerard F.; Leclercq, Dominique Tetrahedron Letters, 1983 , vol. 24, # 40 p. 4323 - 4326

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Citation Number: 11

Abstract

Abstract SN 2 (P) reactions of chlorophosphates, which take place with inversion of configuration, are highly dependent upon the nature of the nucleophile. On the contrary, exocyclic substitutions of five-membered ring chlorophosphates with retention show a marked kinetic levelling effect.