Synlett

Copper-catalyzed conjugate addition of a bis (triorganosilyl) zinc and a methyl (triorganosilyl) magnesium

M Oestreich, B Weiner

Index: Oestreich, Martin; Weiner, Barbara Synlett, 2004 , # 12 p. 2139 - 2142

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Citation Number: 13

Abstract

Abstract A practical copper-catalyzed conjugate silylation of α, β-unsaturated carbonyl compounds 4 utilizing bis (triorganosilyl) zinc reagent 3 is described. Moreover, mixed methyl (triorganosilyl) magnesium 7 also transfers its silyl ligand to simple enones 4 under copper catalysis.

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