Journal of fluorine chemistry

Zur disproportionierung der phenylfluorphosphane (C6H5) 2PF und (C6H5) PF2

L Riesel, J Haenel, G Ohms

Index: Riesel, L.; Haenel, J.; Ohms, G. Journal of Fluorine Chemistry, 1988 , vol. 38, p. 335 - 340

Full Text: HTML

Citation Number: 11

Abstract

Abstract Ph 2 P-PF 2 Ph 2 has been identified by means 19 F-and 31 P-NMR spectroscopy as an intermediate product of the disproportionation of Ph 2 PF. The disproportionation is catalyzed by acids. The reaction mechanism is discussed. PhPF 2 disproportionates faster in solution in acetonitrile than neat, forming (PhP) 6, instead of (PhP) 5.