Reversible Grignard and organolithium reactions
RA Benkeser, MP Siklosi…
Index: Benkeser,R.A. et al. Journal of the American Chemical Society, 1978 , vol. 100, p. 2134 - 2139
Full Text: HTML
Citation Number: 72
Abstract
Abstract: Numerous examples are given of the reversible addition of allylic-type Grignard and organolithium reagents to a variety of ketone substrates. The role of steric hindrance in these reversible additions is clearly demonstrated. Procedures have been devised for the preparation of isomerically pure a-methallylcarbinols derived from the crotyl organometallic. The ketones which form occasionally when the alkoxides of the a-methallylcarbinols ...
Related Articles:
Allylchlorotins as allylating agents of acyl chlorides
[Gambaro, Alessandro; Peruzzo, Valerio; Marton, Daniele Journal of Organometallic Chemistry, 1983 , vol. 258, # 3 p. 291 - 296]
Preparation and reactions of masked allylic organozinc reagents
[Jones, Philip; Knochel, Paul Journal of Organic Chemistry, 1999 , vol. 64, # 1 p. 186 - 195]
[Dubois, Jacques-Emile; Lion, Claude; Arouisse, Abdelmajid Bulletin des Societes Chimiques Belges, 1984 , vol. 93, # 12 p. 1083 - 1088]
[Dubois, Jacques-Emile; Lion, Claude; Arouisse, Abdelmajid Bulletin des Societes Chimiques Belges, 1984 , vol. 93, # 12 p. 1083 - 1088]
[Benkeser,R.A. et al. Journal of the American Chemical Society, 1969 , vol. 91, # 1 p. 132 - 137]