Photochemical transformations. 19. Photosensitized reactions of. beta.-methylallyl chloride

SJ Cristol, RJ Daughenbaugh…

Index: Cristol,S.J. et al. Journal of the American Chemical Society, 1977 , vol. 99, p. 6347 - 6353

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Citation Number: 5

Abstract

Abstract: Photochemical reactions and reactivities of P-methylallyl chloride, sensitized by acetone and by benzene, have been studied. The principal products were an isomer, 1- chloro-1-methylcyclopropane, and a dimer, 5-chloro-4-chloromethyl-2, 4-dimethyl-I-pentene. Smaller amounts of other CS products were also found. The ratio of isomerization to dimerization was markedly dependent upon sensitizer and upon the concentration of ...