Simple and highly efficient catalytic thiocyanation of aromatic compounds in aqueous media

…, M Mokhlesi, FD Panah, S Sajjadifar

Index: Khazaei, Ardeshir; Zolfigol, Mohammad Ali; Mokhlesi, Mohmmad; Panah, Fateme Derakhshan; Sajjadifar, Sami Helvetica Chimica Acta, 2012 , vol. 95, # 1 p. 106 - 114

Full Text: HTML

Citation Number: 31

Abstract

Abstract Two simple, mild, and efficient procedures for the thiocyanation of N-heterocycles, substituted anilines (electron-rich and electron-deficient), and N-substituted aromatic amines at room temperature are reported (Table 3). The first uses H 2 O 2 as pollution-free oxidant and the second H 5 IO 6; both with the reagent potassium thiocyanate in H 2 O as solvent. These procedures provided the target thiocyanates after a short reaction time in good to ...