Alkaline solvolysis of diaminophosphates

J Mollin, J Láznička, F Kašpárek

Index: Mollin, Jiri; Laznicka, Jiri; Kasparek, Frantisek Collection of Czechoslovak Chemical Communications, 1983 , vol. 48, # 1 p. 232 - 242

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Citation Number: 3

Abstract

Abstract Mechanism of alkaline solvolysis of phenyl diaminophosphates is discussed on the basis of its selectivity, activation entropy and steric effects. All methods used show that the reaction proceeds by SN 2 mechanism via an intermediate, containing a pentavalent phosphorus.