The Rearrangement of Some Substituted Allyl Alcohols to their Isomeric Ketones1
AS Dreiding, JA Hartman
Index: Dreiding; Hartman Journal of the American Chemical Society, 1956 , vol. 78, p. 1216
Full Text: HTML
Citation Number: 11
Abstract
It has been shown that the enolic forms of some 8-dicarbonyl compounds are reduced by an excess of lithium aluminum hydride to give one or a pair of substituted allyl alcohols, the number being dependent on the symmetry of P-dicarbonyl compo~ nd.~ A pair of allyl alcohols obtained by such a procedure is usually characterized by their susceptibility to the acid-catalyzed oxotropic rearrangement which results in the more stable isomer. However, ...
Related Articles:
Catalytic Deprotection of Acetals in Basic Solution with a Self??Assembled Supramolecular “Nanozyme”
[Pluth, Michael D.; Bergman, Robert G.; Raymond, Kenneth N. Angewandte Chemie - International Edition, 2007 , vol. 46, # 45 p. 8587 - 8589]
Oxidative Cleavage of Oximes with Silica??Gel??Supported Chromic Acid in Nonaqueous Media
[Ali, Mohammed Hashmat; Greene, Stacie; Wiggin, Candace J.; Khan, Saira Synthetic Communications, 2006 , vol. 36, # 12 p. 1761 - 1767]
[Shimizu, Isao; Tsuji, Jiro Journal of the American Chemical Society, 1982 , vol. 104, # 21 p. 5844 - 5846]
A convenient palladium-catalyzed aerobic oxidation of alcohols at room temperature
[Schultz, Mitchell J.; Park, Candice C.; Sigman, Matthew S. Chemical Communications, 2002 , # 24 p. 3034 - 3035]
[Lenze, Matthew; Sedinkin, Sergey L.; Bauer, Eike B. Journal of Molecular Catalysis A: Chemical, 2013 , vol. 373, p. 161 - 171]