An intramolecular, Schmidt reaction of an alkyl azide with a carbocation. The generation and rearrangement of a conformationally restricted secondary …
WH Pearson, JM Schkeryantz
Index: Pearson, William H.; Schkeryantz, Jeffrey M. Tetrahedron Letters, 1992 , vol. 33, # 37 p. 5291 - 5294
Full Text: HTML
Citation Number: 46
Abstract
... Chem. Ber., 116 (1983), pp. 1081–1096. Full Text via CrossRef. 10.(a); .a H. Wolff; Org. ... Angew. Chem., 76 (1964), p. 381. Full Text via CrossRef. 14; WH Pearson, JS Schkeryantz; Prepared from cyclohexenone by the following sequence: (1) 3,4-methylenedioxyphenyllithium (2) 1-ethoxy-1-(trimethylsilyloxy)ethene, LiClO 4 : (3) LiAlH 4 : (4) MSCl, NEt 3 : (5) n-Bu 4 N 3 , THF. For the lithium perchlorate-promoted substitution of allytic alcohols, see: J. Org. ...
Related Articles:
An efficient synthesis of (±)-crinane using an intramolecular azide-olefin cycloaddition
[Schkeryantz, Jeffrey M.; Pearson, William H. Tetrahedron, 1996 , vol. 52, # 9 p. 3107 - 3116]
Alkaloid synthesis via intramolecular ene reactions. 1. Application to (.+-.)-crinane
[Keck,G.E.; Webb,R.R. Journal of the American Chemical Society, 1981 , vol. 103, p. 3173]
An efficient synthesis of (±)-crinane using an intramolecular azide-olefin cycloaddition
[Schkeryantz, Jeffrey M.; Pearson, William H. Tetrahedron, 1996 , vol. 52, # 9 p. 3107 - 3116]
An efficient synthesis of (±)-crinane using an intramolecular azide-olefin cycloaddition
[Schkeryantz, Jeffrey M.; Pearson, William H. Tetrahedron, 1996 , vol. 52, # 9 p. 3107 - 3116]