Journal of the Chemical Society (Resumed)

594. The conversion of carbamoylmethyl thiolsulphates into thio-oxamides; a new variant of the Willgerodt–Kindler reaction

B Milligan, JM Swan

Index: Milligan; Swan Journal of the Chemical Society, 1959 , p. 2969,2976

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Citation Number: 12

Abstract

By heating thiolsulphates with amines we hoped initially to synthesise sulphenamides according to the equation R* S* SO, Na+ R'vNH, __+ RS-NHR'+ NaHSO,. Such sulphenamides derived from (I) would be hardly distinguishable by analysis (two hydrogen

Selective oxidative carbonylation of amines to oxamides and ureas catalyzed by palladium complexes

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Reactivity of carbamoyl radicals. A new, general, convenient free-radical synthesis of isocyanates from monoamides of oxalic acid

[Minisci, Francesco; Fontana, Francesca; Coppa, Fausta; Yan, Yong Ming Journal of Organic Chemistry, 1995 , vol. 60, # 17 p. 5430 - 5433]

A novel PdCl 2/ZrO 2–SO 2− 4 catalyst for synthesis of carbamates by oxidative carbonylation of amines

[Shi, Feng; Deng, Youquan; SiMa, Tianlong; Yang, Hongzhou Journal of Catalysis, 2001 , vol. 203, # 2 p. 525 - 528]