. beta.-(N, N-Dialkylamino) ethyl arylthiosulfonates: new simulants for O-ethyl S-[2-(diisopropylamino) ethyl] methylphosphonothioate

…, JK Ray, S Kasperowicz, RM Przeslawski…

Index: Davis, Franklin A.; Ray, Jayanta K.; Kasperowicz, Steve; Przeslawski, Robert M.; Durst, H. Dupont Journal of Organic Chemistry, 1992 , vol. 57, # 9 p. 2594 - 2599

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Citation Number: 11

Abstract

@-(NJV-Dialkylamino) ethyl arylthiosulfonates 2, new simulants for the hydrolysis and oxidation chemistry of VX (l), are prepared in good yield by reaction of a potassium arylthiosulfonate with a 2-chloroethylamine. Auraline hydrolysis of 2 results in cleavage of the SS bond to give sulfiiic acids and disulfides. Like VX, oxidation of 2 by N- sulfonyloxaziridine 12 occurs exclusively on nitrogen to give the corresponding amine ...