Chemoselective reduction of organoselenocyanates to diselenides and selenolates
A Krief, C Delmotte, W Dumont
Index: Krief, Alain; Delmotte, Cathy; Dumont, Willy Tetrahedron, 1997 , vol. 53, # 36 p. 12147 - 12158
Full Text: HTML
Citation Number: 70
Abstract
Selenocyanates produce selenolates or diselenides on reaction with metal hydrides (NaH, LiHBEt3, LiBH4, NaBH4). The former transformation is performed with 2 molar equivalents of sodium hydride or lithium triethyl borohydride or 1.25 molar equivalent of metal borohydrides. The second one is performed with lower amount of reducing agent (1 molar equivalent of sodium hydride or lithium triethyl borohydride or 0.25 equivalent of metal ...
Related Articles:
General synthesis of alkyl phenyl selenides from organic halides mediated by zinc in aqueous medium
[Bieber, Lothar W.; De Sa, Ana C.P.F.; Menezes, Paulo H.; Goncalves, Simone M.C. Tetrahedron Letters, 2001 , vol. 42, # 28 p. 4597 - 4599]
[Narayanaperumal, Senthil; Alberto, Eduardo E.; Gul, Kashif; Kawasoko, Cristiane Yuriko; Dornelles, Luciano; Rodrigues, Oscar E.D.; Braga, Antonio Luiz Tetrahedron, 2011 , vol. 67, # 25 p. 4723 - 4730]
[Beletskaya; Sigeev; Peregudov; Petrovskii Russian Journal of Organic Chemistry, 2001 , vol. 37, # 10 p. 1463 - 1475]
[Nazari, Mohammad; Movassagh, Barahman Tetrahedron Letters, 2009 , vol. 50, # 4 p. 438 - 441]
[Nazari, Mohammad; Movassagh, Barahman Tetrahedron Letters, 2009 , vol. 50, # 4 p. 438 - 441]