The Journal of Organic Chemistry

Metalation reactions. III. Metalation of octadecynols and octadecynyl methyl ethers

J Klein, E Gurfinkel

Index: Klein,J.; Gurfinkel,E. Journal of Organic Chemistry, 1969 , vol. 34, # 12 p. 3952 - 3958

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Citation Number: 7

Abstract

600-which takes place during the carbonation reaction has been shown to occur in other instance^.^ However, the introduction of the second carboxyl group in this case is not due to such a reaction, in view of the gradual rise in the percentage of diacids with the time of reaction. A higher ratio of di-to monocarboxylic acids would be expected at the beginning of the reaction, when a larger excess of butyllithium was present, should the formation of ...