Carbenic philicity: 6, 6-dimethylfulvene as an indicator substrate

…, LA Perez, K Krogh-Jespersen

Index: Moss, Robert A.; Young, Claire M.; Perez, Leon A.; Krogh-Jespersen, Karsten Journal of the American Chemical Society, 1981 , vol. 103, # 9 p. 2413 - 2415

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Citation Number: 25

Abstract

& $" P='#'EA'# ETEhSE+ hAhA where $ ETE@ ETA are the efficiencies of scavenging 3A* and 3E* by DBA and+ E4 is the efficiency of exciplex formation over all other modes of deactivation of A*.(6) Experimentally, plots of k vs.[Xy] are not linear but curve upwards. This curvature may reflect the inadequacy of the kinetic treatment based on Scheme I, at the high Xy concentrations used here, where Xy is becoming the solvent. Also, a three-component ...