Flash Generation of a Highly Reactive Pd Catalyst for Suzuki–Miyaura Coupling by Using a Flow Microreactor

A Nagaki, N Takabayashi, Y Moriwaki…

Index: Nagaki, Aiichiro; Takabayashi, Naofumi; Moriwaki, Yuya; Yoshida, Jun-Ichi Chemistry - A European Journal, 2012 , vol. 18, # 38 p. 11871 - 11875

Full Text: HTML

Citation Number: 19

Abstract

Recently, we proposed the concept of flash chemistry,[1] in which extremely fast reactions are conducted in a controlled manner by using flow microreactors;[2–4] unstable reactive species are generated quickly and are used in a subsequent reaction before they decompose by virtue of their short residence time.[5] Herein, we show an application of flash chemistry in catalyst generation. A highly reactive short-lived catalyst precursor is ...

Related Articles:

Synthesis of Biaryls via Pd-Catalyzed Decarboxylative Coupling of Substituted Benzoic Acids with Phenylboronic Acids

[Wang, Anwei; Li, Xiujian; Liu, Jidan; Gui, Qingwen; Chen, Xiang; Tan, Ze; Xie, Kai Synthetic Communications, 2014 , vol. 44, # 2 p. 289 - 295]

Synthesis of biaryls via decarboxylative Pd-catalyzed cross-coupling reaction

[Becht, Jean-Michel; Catala, Cedric; Le Drian, Claude; Wagner, Alain Organic Letters, 2007 , vol. 9, # 9 p. 1781 - 1783]

Palladium catalyzed Suzuki–Miyaura coupling with aryl chlorides using a bulky phenanthryl N-heterocyclic carbene ligand

[Song, Chun; Ma, Yudao; Chai, Qiang; Ma, Chanqin; Jiang, Wei; Andrus, Merritt B. Tetrahedron, 2005 , vol. 61, # 31 p. 7438 - 7446]

Palladium-catalyzed cross-coupling reactions of highly hindered, electron-rich phenol triflates and organostannanes

[Saa, Jose M.; Martorell, Gabriel; Garcia-Raso, Angel Journal of Organic Chemistry, 1992 , vol. 57, # 2 p. 678 - 685]

Biaryl Synthesis via Decarboxylative Pd-Catalyzed Reactions of Arenecarboxylic Acids and Diaryliodonium Triflates

[Becht, Jean-Michel; Le Drian, Claude Organic Letters, 2008 , vol. 10, # 14 p. 3161 - 3164]

More Articles...