Heats of formation of [2.2] paracyclophane-1-ene and [2.2] paracyclophane-1, 9-diene-An experimental study

A de Meijere, SI Kozhushkov, K Rauch…

Index: Beckhaus; Ruechardt; Kozhushkov; Belov; Verevkin; De Meijere Journal of the American Chemical Society, 1995 , vol. 117, # 48 p. 11854 - 11860

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Citation Number: 11

Abstract

The enthalpies of formation [Δ (g)] of tricyclo [8.2. 2.24, 7] hexadeca-1 (13), 2, 4 (16), 5, 7 (15), 10 (14), 11-heptaene (2, 1, 2-dehydro [2.2] paracyclophane or [2.2] paracyclophane-1- ene) and tricyclo [8.2. 2.24, 7] hexadeca-1 (13), 2, 4 (16), 5, 7 (15), 8, 10 (14), 11-octaene (3, 1, 2, 9, 10-dehydro [2.2] paracyclophane or [2.2] paracyclophane-1, 9-diene) have been determined by measuring their heats of combustion in a microcalorimeter and their heats ...