On the Photochemical Hydrogen Shifts in Arylcycloheptatrienes

T Tezuka, M Kimura, A Sato, T Mukai

Index: Tezuka,T. et al. Bulletin of the Chemical Society of Japan, 1970 , vol. 43, p. 1120 - 1126

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Citation Number: 15

Abstract

Photochemically-induced hydrogen shifts in 7-(p-chlorophenyl), 7-phenyl, 7-(p- methoxyphenyl) and 7-p-tolylcycloheptatrienes (Ia—d) were studied. The possibility of hydrogen 1, 7 and 1, 3 shifts in these compounds was examined on both experimental and theoretical grounds. It was concluded that the hydrogen 1, 7 shift is the only suprafacial hydrogen shift possible in the excited cycloheptatriene system. In this study all the isomers ...

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