ADMET Synthesis of polyolefins targeted for biological applications
TE Hopkins, KB Wagener
Index: Hopkins, Timothy E.; Wagener, Kenneth B. Macromolecules, 2004 , vol. 37, # 4 p. 1180 - 1189
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Citation Number: 67
Abstract
A series of “N-terminus” amino acid and peptide branched, chiral polyolefins, termed bio- olefins, have been prepared using acyclic diene metathesis (ADMET) polycondensation chemistry, using a minimal amount of solvent and Grubbs' second generation catalyst. The carboxylic acid functional groups were protected with methyl, benzyl, and tert-butyl esters to enhance both the polymerizability of the monomers themselves and the solubility of the ...
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