Base-induced and-directed elimination and rearrangement of perhydronaphthalene-1, 4-diol monosulfonate esters. Total synthesis of (.+-.)-alloaromadendrane-4. …

LHD Jenniskens, JBPA Wijnberg…

Index: Jenniskens, Louis H. D.; Wijnberg, Joannes B. P. A.; Groot, Aede de Journal of Organic Chemistry, 1991 , vol. 56, # 23 p. 6585 - 6591

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Citation Number: 33

Abstract

Conclusion The present paper reports a new conformational enantiomerism in the y-CDx cavity. We regard the 1-y-CDx complex as a model for studying the mechanism of chiral recognition by CDxs in aqueous solutions. The relative enantioselectivities were conveniently evaluated from the intensities of the bisignate CD signals of the inclusion complexes. y-CDx is the most effective host molecule, where a carboxylate anion of a ...