Selective Electrosynthesis of (Trimethylsilyldifluoro) methylbenzene, a PhCF2-Precursor; Conditions for a Molar Scale Preparation without HMPA
…, MP Léger-Lambert, C Biran, F Serein-Spirau…
Index: Clavel; Leger-Lambert; Biran; Serein-Spirau; Bordeau; Roques; Marzouk Synthesis, 1999 , # 5 p. 829 - 834
Full Text: HTML
Citation Number: 13
Abstract
Abstract: Electrochemical reductive silylation of trifluoromethylbenzene by the sacrificial anode technique selectively led, in a THF/DMPU mixture instead of THF/HMPA and according to the charge passed, to the corresponding mono-, bis-or tris-trimethylsilyl derivatives, respectively PhCF2TMS, PhCF (TMS) 2 and PhC (TMS) 3. This reaction, without any chemical equivalent, was extended to a molar scale synthesis, using a tubular flow ...
Related Articles:
[Bassindale,A.R. et al. Journal of Organometallic Chemistry, 1969 , vol. 20, p. 49 - 56]
Electrochemical Stepwise Synthesis of Poly [2, 5-(silanylene) thiophene] Precursors
[Biran; Bordeau; Bonafoux; Deffieux; Duprat; Jouikov; Leger-Lambert; Moreau; Serein-Spirau Journal de Chimie Physique et de Physico-Chimie Biologique, 1996 , vol. 93, # 4 p. 591 - 600]
Electrochemical Stepwise Synthesis of Poly [2, 5-(silanylene) thiophene] Precursors
[Biran; Bordeau; Bonafoux; Deffieux; Duprat; Jouikov; Leger-Lambert; Moreau; Serein-Spirau Journal de Chimie Physique et de Physico-Chimie Biologique, 1996 , vol. 93, # 4 p. 591 - 600]