Synthesis of the unusual metabolite carboxyphosphonoenolpyruvate. Cloning and expression of carboxyphosphonoenolpyruvate mutase

S Freeman, SJ Pollack, JR Knowles

Index: Freeman, Sally; Pollack, Scott J.; Knowles, Jeremy R. Journal of the American Chemical Society, 1992 , vol. 114, # 1 p. 377 - 378

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Citation Number: 11

Abstract

The carbon-phosphorus bond of most naturally occurring phosphonates derives from a 1, 3- phospho group transfer reaction between phosphoenolpyruvate (1) and phosphonopyruvate (2) The equilibrium for this rearrangement, which is catalyzed by phosphoenolpyruvate ...