Journal of molecular structure

Conformational stability of ethyl chlorogermane from temperature-dependent FT-IR spectra of krypton solutions and r 0 structural parameters of methyl chlorogermane …

JR Durig, C Pan, GA Guirgis

Index: Durig, James R; Pan, Chunhua; Guirgis, Gamil A Journal of Molecular Structure, 2002 , vol. 607, # 2-3 p. 117 - 132

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Citation Number: 14

Abstract

The Raman spectra (3200–30cm− 1) of liquid and solid, and infrared spectra of gaseous and solid ethyl chlorogermane, CH3CH2GeH2Cl, have been recorded. Variable temperature (− 105 to− 150° C) studies of the infrared spectra of the sample dissolved in liquid krypton have been carried out. From these data, the enthalpy difference has been determined to be 143±30cm− 1 (1.71±0.36 kJmol− 1), with the more stable form, the ...