Chiroptical properties of the non-planar nitrosamine chromophore in N-nitrosaziridines

…, GK Kadorkina, RG Kostyanovsky, A Rauk

Index: Shustov, Gennadii V.; Kachanov, Alexander V.; Kadorkina, Gulnara K.; Kostyanovsky, Remir G.; Rauk, Arvi Journal of the Chemical Society, Chemical Communications, 1992 , # 9 p. 705 - 706

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Abstract

The sign of the long-wavelength Cotton effect in the circular dichroism (CD) spectra of N- nitrosaziridines, possessing a non-planar nitrosamine chromophore, is determined by the intrinsic chirality of the chromophore, as in the cases of N-acylaziridines and gauche- cyclopropylketones.