Journal of fluorine chemistry

Electrochemical fluorosulfation of perfluoroallylbenzene

SR Sterlin, VA Grinberg

Index: Sterlin, Sergei R.; Grinberg, Vitali A. Journal of Fluorine Chemistry, 2003 , vol. 122, # 2 p. 183 - 187

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Citation Number: 3

Abstract

Perfluoroallylbenzene (I) can be isomerized under the action of HSO3F to form perfluoropropenylbenzene (in the form of a mixture of cis-and trans-isomers) which undergoes anodic oxidation in HSO3F to give α, β-bis (fluorosulfonyloxy) perfluoropropylbenzene (III). Reaction of III with CsF in tetraglyme gives perfluoro-2- methylbenzoxolene (XII), whereas III is converted to perfluoromethylphenyl-α-dione (IX) by ...