The Chemistry of Dicyclopentadiene. II. Addition-Rearrangement with Acids

HA Bruson, TW Riener

Index: Bruson; Riener Journal of the American Chemical Society, 1945 , vol. 67, p. 1178

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Citation Number: 23

Abstract

When dry hydrogen chloride is bubbled into dry dicyclopentadiene at 60-70'practically no addition of the hydrogen chloride to the double bonds of the hydrocarbon occurs. However, if a small amount of water is present, addition of the hydrogen chloride takes place readily to form a monohydrochloride. This reaction product still contains one double bond even though an excess of hydrogen chloride be used. The chlorine atom in the dicyclopentadiene ...