Copper??Catalyzed Arylative Meyer–Schuster Rearrangement of Propargylic Alcohols to Complex Enones Using Diaryliodonium Salts

BSL Collins, MG Suero…

Index: Collins, Beatrice S. L.; Suero, Marcos G.; Gaunt, Matthew J. Angewandte Chemie - International Edition, 2013 , vol. 52, # 22 p. 5799 - 5802

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Citation Number: 66

Abstract

Propargylic alcohols are among the most useful bifunctional building blocks available to the synthetic chemist. Generated through well-established and robust strategic bond-forming reactions, propargylic alcohols have provided a fertile testing ground upon which to explore new catalytic activation pathways. Many previously unknown catalytic transformations have been discovered starting from these readily assembled molecules and have greatly ...