The synthesis, structure, and chemistry of 10-Pn-3 systems: tricoordinate hypervalent pnicogen compounds

AJ Arduengo III, CA Stewart, F Davidson…

Index: Arduengo, Anthony J.; Stewart, Constantine A.; Davidson, Fredric; Dixon, David A.; Becker, James Y.; et al. Journal of the American Chemical Society, 1987 , vol. 109, # 3 p. 627 - 646

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Citation Number: 69

Abstract

Abstract: A set of previously unknown tricoordinate hypervalent pnictogen compounds, 10- Pn-3 ADPnO, has been synthesized. The chemistry of these systems has been studied. Reactions with alcohols, a-dicarbonyl compounds, halogens, transition metals, protic acids, and acetylenes are among the chemistry described. In general, it was found that 10-As-3 ADAsO and 10-Sb-3 ADSbO systems behave similarly and offer different chemistry from ...