" d-Orbital effects" in silicon-substituted. pi.-electron systems. XI. Syntheses and properties of the isomeric bis (trimethylsilyl)-1, 3-butadienes
H Bock, H Seidl
Index: Bock,H.; Seidl,H. Journal of the American Chemical Society, 1968 , vol. 90, p. 5694 - 5700
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Citation Number: 62
Abstract
Abstract: The isomeric 1, 2-, 1, 3-, 1, 4-, and 2, 3-bis (trimethylsilyl)-l, 3-butadienes have been synthesized, and their vertical ionization energies, characteristic vibrational frequencies,'H nmr signals, half-wave reduction potentials, radical-anion coupling constants, and electronic transitions have been determined. The different properties rela-tive to those of the corresponding alkyl derivatives are discussed in terms of inductive polarization+ ZsiRa ...
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