The Journal of Organic Chemistry

Notes-2, 2-Dinitroethylamine and Derivatives

M Kamlet, J Dacons

Index: Kamlet,M.J.; Dacons,J.C. Journal of Organic Chemistry, 1961 , vol. 26, p. 3005 - 3008

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Citation Number: 8

Abstract

The reaction of l, l, l-trinitroethane with methanolic ammonia at room temperature proceeded smoothly with only a mild exotherm to yield I1 (85%), the by-product ammonium nitrite decomposing under the conditions of the reaction to nitrogen and water. With dimethylamine in aqueous methanol the yield of the N, Ndimethyl derivative 111 was 65%. The products in both instances were only slightly soluble and precipitated directly from the reaction ...