Efficient Borylation of Reactive Aryl Halides with MPBH (4, 4, 6-Trimethyl-1, 3, 2-dioxaborinane)
N PraveenGanesh, E Demory, C Gamon, V Blandin…
Index: Praveenganesh, Nageswaran; Demory, Emilien; Gamon, Christine; Blandin, Veronique; Chavant, Pierre Y. Synlett, 2010 , # 16 p. 2403 - 2406
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Citation Number: 4
Abstract
Abstract The combination of 4, 4, 6-trimethyl-1, 3, 2-dioxaborinane, a particularly stable and inexpensive borylation reagent, and Buchwald's palladium catalyst provides a simple, fast, cost-effective borylation of electron-rich, reactive iodides, bromides, and triflates to produce stable, easily purified boronic esters.
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