Zinc??Catalyzed [4+ 3] Cycloaddition with Concomitant Furan Annulation: Formation of Cyclohepta [b] Furans

…, YF Qiu, MJ Zhong, PX Zhou, YM Liang

Index: Song, Bo; Li, Lian-Hua; Song, Xian-Rong; Qiu, Yi-Feng; Zhong, Mei-Jin; Zhou, Ping-Xin; Liang, Yong-Min Chemistry - A European Journal, 2014 , vol. 20, # 20 p. 5910 - 5913

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Citation Number: 13

Abstract

Abstract A convenient zinc-promoted [4+ 3] cycloaddition of a carbonyl ene–yne with simple dienes was first achieved. This reaction provided an efficient strategy to prepare various cyclohepta [b] furan rings by cascade cycloadditions. Additionally, a multicomponent reaction of dione, alkynal, and diene was also reported, which exhibited a novel strategy for selective creations of C [BOND] O bonds and C [BOND] C bonds.

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