Total synthesis of amphilectane-type diterpenoids:(±)-8, 15-diisocyano-11 (20)-amphilectene

…, M Llinas-Brunet, RM Oballa

Index: Piers; Llinas-Brunet; Oballa Canadian Journal of Chemistry, 1993 , vol. 71, # 9 p. 1484 - 1494

Full Text: HTML

Citation Number: 12

Abstract

A total synthesis of the structurally novel, antimicrobial diterpenoid (±)-8, 15-diisocyano-11 (20)-amphilectene (2) is described. Alkylation of 2-methoxycarbonyl-3-methylcyclohexanone (13) with (E)-1-(tert-butyldimethylsiloxy)-6-iodo-3-(trimethylstannyl)-2-hexene (14) provided,

Related Articles:

Ring opening of cyclopropylketones induced by photochemical electron transfer

[Cossy, Janine; Furet, Nathalie; BouzBouz, Samir Tetrahedron, 1995 , vol. 51, # 43 p. 11751 - 11764]

Preparation and alkylation of cyclic β-trimethylstannyl α, β-unsaturated esters. A new, general annulation sequence

[Piers, Edward; Tse, Hoi Lun Allan Tetrahedron Letters, 1984 , vol. 25, # 30 p. 3155 - 3158]

More Articles...