Bis (2-alkylpyrrolidin-1-yl) methylidenes as chiral acyclic diaminocarbene ligands
DR Snead, S Inagaki, KA Abboud, S Hong
Index: Snead, David R.; Inagaki, Sebastien; Abboud, Khalil A.; Hong, Sukwon Organometallics, 2010 , vol. 29, # 7 p. 1729 - 1739
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Citation Number: 38
Abstract
Chiral acyclic diaminocarbene (ADC) ligands were built featuring the 2-alkylpyrrolidine subunit, and the carbenes have been ligated to palladium and rhodium centers. Structural features were investigated through X-ray analysis including the steric parameter,% V Bur, and the catalytic performance was tested in the Suzuki reaction and 1, 2 addition of 1- naphthylboronic acid to o-anisaldehyde.
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