Kinetics and products of the reactions of nitrate radical with monoalkenes, dialkenes, and monoterpenes

I Barnes, V Bastian, KH Becker…

Index: Barnes, Ian; Bastian, Volker; Becker, Karl H.; Tong, Zhu Journal of Physical Chemistry, 1990 , vol. 94, p. 2413 - 2419

Full Text: HTML

Citation Number: 142

Abstract

Rate constants for the reactions of NO3 with a number of aliphatic mono-and dialkenes and monoterpenes have been determined in a 420 1 reaction chamber at I-bar total pressure of synthetic air by 298 K with a relative kinetic method. The products of these reactions have been investigated also at I-bar total pressure of synthetic air with in situ FT-IR spectrometry and gas chromatography. In all cases, the initial formation of thermally unstable nitrooxy- ...